泥岩有水热解产生低分子量有机酸实验研究   总被引：1，自引：0，他引：1  

薛莲  李东  刘建平  陈传平 《地球化学》2011,(4):381-386

直接采用泥岩岩屑进行有水热解,测定实验后水溶液中几种常见低分子量有机酸.结果表明,在实验的水溶液中检测到了丰富的低分子量有机酸,组成上主要为一元羧酸,其中又以乙酸占优势.讨论了不同热解条件对有机酸产率以及组成的影响.实验结果表明,有机酸总量随加热温度和时间增加而增加,并且溶液中不同有机酸相对组成也发生变化.当温度高于1...  相似文献   

克拉玛依科博馆倾斜结构抗震设计     

赵楠 《地震工程与工程振动》2011,31(2):111-117

结合克拉玛依市科技博物馆工程,对超限倾斜结构设定性能设计目标,并针对性能目标提出抗震措施及抗震构造措施.考虑结构材料的非线性属性,采用静力非线性分析方法,分析倾斜框架-剪力墙结构在地震作用下的响应,尤其是结构在罕遇地震作用下的非线性动力特性.结果表明,结构在罕遇地震下也是安全可靠的,剪力墙尚处在弹性范围,未出现塑性铰,...  相似文献   

东昆仑造山带东段哈图沟–清水泉–沟里韧性剪切带塑性变形及动力学条件研究   总被引：1，自引：0，他引：1  

李小兵  裴先治  陈有炘  刘成军  李佐臣  李瑞保  陈国超  魏博 《大地构造与成矿学》2015,(2)

东昆仑造山带东段哈图沟–清水泉–沟里韧性剪切带记录了多个旋回的造山作用,本文通过对韧性剪切带中石英c轴组构和显微构造特征测试分析,探讨东昆仑造山带东段陆块间俯冲拼合及地壳伸展减薄的形成机制。结果显示,韧性剪切带变形温度介于380~650℃之间,形成环境为中–高绿片岩相到低角闪岩相,剪切带内差异应力值介于173~509 MPa之间,应变速率介于6.93×10–14~1.43×10–8 s–1之间,主体为10–11~10–10 s–1,显示韧性剪切带变形是快速俯冲作用下的产物,越靠近东昆仑造山带东段东昆中断裂带其变形温度、差异应力值及相应的应变速率值越大,表明东昆仑造山带东段韧性剪切变形中心为东昆中断裂带。利用不同方法所计算出的韧性剪切带运动学涡度值,显示韧性剪切带早期瞬时运动学涡度(0.56~1)对应于东昆仑造山带东段东昆南与东昆仑造山带东段东昆北陆块间俯冲的初始阶段,中后期运动学涡度(0.25~0.91)应当对应于东昆南与东昆北陆块间的俯冲碰撞阶段,最晚期的C′瞬时运动学涡度(0.19~0.51)则对应于后造山的伸展阶段。通过石英c轴组构结合其宏微观构造特征,认为东昆中构造带至少经历了3个期次的构造运动,分别为加里东晚期的逆冲兼左行走滑剪切作用、晚海西–印支期的逆冲兼右行走滑剪切作用和燕山早期及之后的脆韧性–脆性的左行走滑剪切作用。  相似文献   

老挝龙湖钾盐矿床沉积碳酸盐碳、氧同位素组成及其对成钾环境的初步指示     

韩元红  马海州  张西营  王琪  罗厚勇  李建森  廖朋  朱军 《大地构造与成矿学》2015,(2)

碳、氧同位素作为反映古沉积环境、成矿物源和水–岩反应等良好的稳定同位素指标,被广泛应用。通过对老挝龙湖钾盐矿区ZK309、ZK301、ZK311和ZK004四个钻孔农波组盐岩上覆泥岩碳、氧同位素组成的分析,讨论了盐岩上覆泥岩沉积的碳、氧同位素组成变化特征及其指示的沉积环境。经分析,所测碳、氧同位素基本代表了碳酸盐碳、氧同位素组成,初步推测这些碳酸盐均为当地自生,受后期改变很少,δ13C和δ18O平均值分别为-5.1‰和-4.6‰,其中δ13C值略高于一般陆相碳酸盐碳同位素最大值–5.69‰,δ18O值介于–2.71‰~–10.8‰之间,ZK309和ZK301钻孔碳、氧同位素相关系数均小于0.7,初步指示盐岩沉积之后沉积环境为陆相。δ13C值略高于–5.69‰,推测是后期盐岩层被淋滤,泥岩层受淋滤后的残余卤水影响的结果,这也解释了蒸发岩沉积层序异常(钾石盐覆盖于光卤石之上)的沉积特征。因此,在本研究中,大气水在泥岩碳、氧同位素的变化中扮演了重要角色。  相似文献   

Simultaneous water and vapour transfer in an unsaturated mudstone in badlands terrain,southwestern Taiwan     

Kohei Higuchi  Masahiro Chigira  Der-Her Lee  Jian-Hong Wu 《地球表面变化过程与地形》2020,45(13):3323-3335

The simultaneous transfer of pore fluid and vapour was studied in the unsaturated shallow subsurface of a Plio-Pleistocene marine mudstone badland slope in southwestern Taiwan during the dry season using field monitoring data and numerical simulations. Data from field monitoring show mass-basis water contents of ~0.05 to ~0.10 that decrease towards the unsaturated ground surface and were invariant during the middle part of the dry season, except for daily fluctuations. In addition, the observed daily fluctuations in water content correlate with fluctuations in bedrock temperature, especially at depths of 2.5–5.0 cm. Periodic increases in water content occurred most notably during the day, when the bedrock temperature showed the greatest increase. Water contents then decreased to the previous state as bedrock temperature decreased during the night. Calculated vapour fluxes within the mudstone during the day increased up to 6 × 10⁻⁶–1 × 10⁻⁵ kg m⁻² s⁻¹, deriving a 0.01–0.02 increase in mass-basis water content at 2.5 cm depth for a 12-h period. This agrees with field monitoring data, suggesting that increases in water content occurred due to vapour intrusions into the bedrock. Pore water electrical conductivity (EC) showed periodic variations due to vapour intrusion, and gradually increased between the ground surface and depths of 2.5–5.0 cm. In contrast, pore water EC gradually decreased between 15 and 40 cm depth. Calculated water fluxes at depths of 2.5–40.0 cm varied from −4 × 10⁻⁶ to −2 × 10⁻⁹ kg m⁻² s⁻¹. These fluxes generated an increase in solute concentrations at the ground surface, with negative values of water flux indicating an upwards movement of water towards the surface. We show that the increase in solute content due to solute transfer from depth is highly dependent on variations in water flux with depth. © 2020 John Wiley & Sons, Ltd.  相似文献   

级配碎石填料大三轴试验及累积塑性应变预测模型     

杨志浩  岳祖润  冯怀平  叶朝良  马德良 《岩土力学》2020,41(9):2993-3002

级配碎石作为重载铁路基床表层的主要填料，其受列车荷载的影响最大。因此，研究级配碎石在循环荷载作用下的动力行为及累积塑性应变演化特征变得尤为重要。首先，通过制备不同细粒含量的级配碎石填料，开展一系列大型动三轴试验，探究细粒含量、围压及动应力幅值对循环荷载作用下试样累积塑性应变的耦合影响机制。其次，基于塑性安定理论，确定不同应力水平下试样的动力行为，得到考虑围压及细粒含量参数的塑性蠕变状态临界动应力计算模型。最后，结合试验数据，建立考虑应力水平及细粒含量参数的塑性蠕变动力行为累积塑性应变预测模型，并明确各参数的物理意义。其研究成果可为既有重载铁路路基健康状态评估及考虑强度、变形综合控制的路基结构设计提供参考。  相似文献   

Material selection for the gas containment system of a compressed natural gas carrier fleet     

《Applied Ocean Research》2016

In this work, the possible exploitation of fiber-reinforced composites in the context of maritime transportation of compressed natural gas (CNG) is investigated. In addition to a more conventional steel configuration, two different fiber materials, carbon and glass, are considered as construction materials for pressure vessels (PVs) to be stored on board ships, with thickness optimized by FEM analysis.The considered scenario is represented by the transportation of CNG from an offshore well to a terminal on shore. Fleets of ships carrying CNG in pressure vessels manufactured with the investigated materials are generated by means of a ship synthesis model (SSM) software and compared on the basis of technical and economical indicators.The choice of the construction material influences considerably the weight of the PVs, which represent a major item of total ship weight and reflects directly on the general transport performances in terms of resistance, seakeeping and reliability in the service. On the other hand, capital as well as operating expenditures are considerably affected by the choice. When exploring the design space, the ship synthesis model is able, at a preliminary stage of the design, to account for the various technical and economical aspects, their implications and relationships. Results are presented of computations carried out in a specific case, identified by the annual gas production and other characteristics of the well terminal and a cruising route for the ships. The comparison is carried out on the basis of the cost per transported unit of gas and of the percentage of success in the transportation process. The computations show that the choice of the PV material has a key influence on the results in terms of optimal number, dimensions and speed of the ships.  相似文献   

Limitations of suction‐controlled triaxial tests in the characterization of unsaturated soils          下载免费PDF全文

X. Zhang 《国际地质力学数值与分析法杂志》2016,40(2):269-296

Behavior of unsaturated soils is influenced by many factors, and the influences of these factors are usually coupled together. Suction‐controlled triaxial (SCTX) tests are considered to allow researchers to investigate influences of individual variables on unsaturated soils under specified stress path with controls of stresses, pore water, and air pressures. In the past 50 years, SCTX testing method has been established as a standard approach to characterize constitutive behavior of unsaturated soils. Most important concepts for modern unsaturated soil mechanics were developed upon results from the SCTX tests. Among these, one of the most important contributions in the constitutive modeling of elasto‐plastic behavior for unsaturated soils is the Barcelona basic model (BBM) proposed by Alonso et al. in 1990. The BBM successfully explained many features of unsaturated soils and received extensive acceptance. However, the SCTX tests are designed based upon the divide‐and‐conquer approach in which an implicit assumption is used: soil behavior is stress‐path independent. However, it is well‐established that unsaturated soil behavior is elasto‐plastic and stress‐path dependent. It is found that the SCTX tests in fact cannot control the stress path of an unsaturated soil during loading. This incapability, in combination with complicated loading/collapse behavior of unsaturated soils, makes the SCTX tests for characterizing unsaturated soil questionable. This paper discusses the limitations of the SCTX tests in the characterization of unsaturated soils. A possible solution to the problem was proposed based on a newly developed modified state surface approach. The discussions are limited for isotropic conditions. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Three‐dimensional shakedown solutions for anisotropic cohesive‐frictional materials under moving surface loads     

Juan Wang  Hai‐Sui Yu 《国际地质力学数值与分析法杂志》2014,38(4):331-348

Previous work on three‐dimensional shakedown analysis of cohesive‐frictional materials under moving surface loads has been entirely for isotropic materials. As a result, the effects of anisotropy, both elastic and plastic, of soil and pavement materials are ignored. This paper will, for the first time, develop three‐dimensional shakedown solutions to allow for the variation of elastic and plastic material properties with direction. Melan's lower‐bound shakedown theorem is used to derive shakedown solutions. In particular, a generalised, anisotropic Mohr–Coulomb yield criterion and cross‐anisotropic elastic stress fields are utilised to develop anisotropic shakedown solutions. It is found that shakedown solutions for anisotropic materials are dominated by Young's modulus ratio for the cases of subsurface failure and by shear modulus ratio for the cases of surface failure. Plastic anisotropy is mainly controlled by material cohesion ratio, the rise of which increases the shakedown limit until a maximum value is reached. The anisotropic shakedown limit varies with frictional coefficient, and the peak value may not occur for the case of normal loading only. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Macroscopic criteria for Green type porous materials with spheroidal voids: application to double porous materials          下载免费PDF全文

W. Q. Shen  J.‐F. Shao  D. Kondo 《国际地质力学数值与分析法杂志》2017,41(13):1453-1473

Combined effects of matrix plastic compressibility and void shape are investigated for ductile porous materials. To this end, a spheroidal volume containing a confocal spheroidal (prolate or oblate) void subjected to uniform strain rate boundary conditions has been first studied. A Green type matrix is chosen as a prototype for investigating effects of plastic compressibility. This is carried out by using a kinematics limit analysis theory from which a closed‐form expression of the macroscopic criterion is established for the considered class of materials. These results are then extended to ductile porous materials made up of a green matrix containing randomly oriented spheroidal voids. In the framework of a two‐step homogenization procedure, the obtained results are implemented to describe the macroscopic behavior of double porous materials involving spherical voids at the microscale and randomly oriented and distributed spheroidal voids at the mesoscale. For validation purpose, the new derived criteria are assessed and validated by comparing their predictions to available upper bounds and numerical data from literature. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献